Chemical Relaxation with Preferential Dissociation from Excited Vibrational Levels
نویسندگان
چکیده
منابع مشابه
Collisional relaxation of highly excited vibrational levels of I2(X)
The relaxation dynamics of vibrationally excited levels of I2(X) are of relevance to the chemical oxygen iodine laser. We have investigated relaxation of 12(vM>20) by pulsed laser techniques. Individual ro-vibrational levels were populated by stimulated emission pumping. Collisionally populated levels were monitored via laser excitation of the D-X transition. Preliminary rate constants for vibr...
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We extend, via a reformulation in terms of Poisson brackets, the method developed previously (Rey et al., J. Phys. Chem. A, 2009, 113, 8949) allowing analysis of the pathways of an excited molecule's ultrafast vibrational relaxation in terms of intramolecular and intermolecular contributions. In particular we show how to ascertain, through the computation of power and work, which portion of an ...
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ژورنال
عنوان ژورنال: Physics of Fluids
سال: 1963
ISSN: 0031-9171
DOI: 10.1063/1.1706888